A unique chemical looping process can convert a wide range of fuels, both solid and gaseous, such as natural gas, coal, petroleum coke (petcoke), methane, biomass, and other industrial process off-gases and materials, into multiple products including hydrogen, synthesis gas (syngas), and steam for power, process and heating. The process inherently isolates a concentrated CO2 stream which can be used for other onsite processes or transported and stored. This unique chemical looping platform is highly scalable and can be applied to a wide array of industrial processes.